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何心伟


何心伟   副教授 博士 硕士生导师

 E-mail: xinweihe@mail.ahnu.edu.cn

 实验室:花津校区理科大楼1129

 办公室:花津校区理科大楼1136

 ORCIDhttp://orcid.org/0000-0002-1974-2464

 

 所受教育

  博士 (安徽师范大学,2015)

  硕士 (安徽师范大学,2009)

  学士 (安徽师范大学,2003)

 职称职位

  20183—2019年3月,香港中文大学化学系,访问学者

  201512至今,安徽师范大学 硕士生导师

  200307至今, 安徽师范大学助教,讲师,副教授 (2015)

 科研项目

  7. 基于苯丙炔胺类化合物的亲核取代-分子内环化串联反应研究.安徽省自然科学基金面上项目 (1808085MB41). 12, 2018.7-2021.6. 主持, 在研.

  6. 基于叠氮化合物和炔烃的多组分反应研究. 安徽省高等学校自然科学研究重点项目(KJ2016A267). 6, 2016.1-2017.12. 主持, 结题.

  5. FeCl3催化的串联反应合成含氮杂环化合物的研究. 安徽师范大学博士科研启动基金项目(2016XJJ110). 4, 2016.1-2018.12. 主持, 结题.

  4. FeCl3催化的串联反应合成香豆素类化合物的应用研究, 安徽省自然科学基金青年基金项目 (1308085QB39), 5, 2013.7-2015.5, 主持.

  3. 3,4,5-三取代-2-噁唑烷酮衍生物的合成研究, 安徽师范大学创新基金项目 (2014cxjj12), 1.2, 2014.7-2016.6, 主持.

  2. 一种香豆素类化合物的绿色合成研究, 安徽师范大学创新基金项目 (2011cxjj12), 1.0, 2012.1-2012.12, 主持.

  1. CuI催化的磺酰基脒类化合物及噁唑酮类衍生物的合成研究, 安徽师范大学人才培育基金项目 (2010rcpy041), 0.3, 2011.1-2012.12, 主持.

 讲授课程

  1. 专业课:化工基础/材料工程基础/化工安全技术/化工安全与环境

  2. 实验课:基础化学实验/综合化学实验/化工专业实验/化工专业实训

  3. 选修课:日用化学品化学/诺贝尔奖与科学精神

 获奖与人才情况

  2019年获安徽省教坛新秀称号

  2019年获安徽师范大学首届郭锐评、陈礼勤奖教金突出贡献奖

  2019年获安徽省第四届普通高校青年教师教学竞赛一等奖

  2019年获安徽师范大学第九届青年教师教学基本功大赛三等奖

  2019年获安徽师范大学美高梅4858线路登录第十一届青年教师讲课大赛一等奖

  2018年获安徽省科学技术奖三等奖(排名第三)

  2017年获安徽师范大学美高梅4858线路登录第六届最受本科生喜欢的青年教师称号

  2016年获安徽师范大学美高梅4858线路登录第五届最受本科生喜欢的青年教师称号

  2015年获安徽省第八届自然科学优秀学术论文三等奖(排名第一)

  2015年获安徽师范大学教坛新秀称号

  2015年获安徽师范大学美高梅4858线路登录第四届最受本科生喜欢的青年教师称号

  2014年获安徽师范大学第四届青年教师教学基本功大赛三等奖

  2014年获安徽师范大学美高梅4858线路登录第六届青年教师讲课大赛一等奖

  2012年获安徽省第七届自然科学优秀学术论文三等奖(排名第三)

 课题组成员

  2023级:孔杨子林(本科毕业于阜阳师范大学)

  2022级:武孟迪(本科毕业于安徽师范大学)

  2021级:刘雅楠(本科毕业于淮北师范大学信息学院)、王德茂(本科毕业于合肥学院)

  2020级:徐可可(本科毕业于淮北师范大学信息学院,2023年毕业后入职于合肥新东方培训学校)

  2019级:段嘉晖(本科毕业于安徽师范大学,2022年毕业后入职于宿州二中)

  2018级:李如雪(本科毕业于南阳师范学院,2021年毕业后就职于淮北市天一中学)

  2017级:谢梦情(本科毕业于淮北师范大学,2020年毕业后就职于安徽中科拓苒药物科学研究有限公司)

  2016级:武玉豪(本科毕业于阜阳师范大学,2019年毕业后就职于无锡市育人教育)

 课题组动态

2023/11/03 祝贺课题组刘雅楠同学的文章被The Journal of Organic Chemistry录用,论文题目为:"Cascade Annulation Strategy for Expeditious Assembly of Hydroxybenzo[c]chromen-6-ones and Their Photophysical Property Studies"

2023/11/01 祝贺课题组王德茂同学的文章被Organic & Biomolecular Chemistry录用,论文题目为:"Synthesis of arene-functionalized fused heterocyclic scaffolds via a regioselective cascade 1,4-conjugate addition/5-exo-dig annulation strategy"

2023/09/20 欢迎孔杨子林同学加入课题组。

2023/06/05 祝贺徐可可同学通过硕士论文答辩并获得硕士学位,感谢徐可可同学为课题组所做的贡献,祝前程似锦!

2022/11/03 祝贺课题组李如雪同学的文章被Chemical Science录用,论文题目为:"An expeditious FeCl3-catalyzed cascade 1,4-conjugate addition/annulation/1,5-H shift sequence for modular access of all-pyrano-moiety-substituted chromenes"

2022/10/26 祝贺课题组徐可可同学的文章被Molecules录用,论文题目为:"Radical-Induced Cascade Annulation/Hydrocarbonylation for Construction of 2-Aryl-4H-chromen-4-ones"。

2022/10/20 祝贺课题组唐强同学的文章被Advance Synthesis & Catalysis 录用,论文题目为:"Metal-Free Cascade 1,4-Conjugate Addition/Selective Annulation Strategy for Divergent Synthesis of Polysubstituted Imidazoles and 4-Alkenylquinazolines"。

2022/09/25 欢迎武孟迪同学加入课题组。

2022/06/15 祝贺段嘉晖同学通过硕士论文答辩并获得硕士学位,感谢段嘉晖同学为课题组所做的贡献,祝前程似锦!

2022/01/12 祝贺课题组唐强同学的文章被European Journal of Organic Chemistry 录用,并被选为“Very Important Paper”,论文题目为:Metal-free Cascade Annulation Approach for Modular Assembly of Alkynyl/Benzoyl Functionalized Quinolines

2021/10/20 祝贺课题组段嘉晖同学获得2021年研究生国家奖学金。

2021/09/20 欢迎刘雅楠、王德茂两位同学加入课题组。

2021/07/30 祝贺课题组段嘉晖同学的文章被Organic Letters 录用,论文题目为:Cascade Lactonization/Benzannulation of Propargylamines with Dimethyl 3-Oxoglutarate for Modular Assembly of Hydroxylated/Arene-Functionalized Benzo[c]chromen-6-ones

2021/06/05 祝贺李如雪同学通过硕士论文答辩并获得硕士学位,感谢李如雪同学为课题组所做的贡献,祝前程似锦!

2021/02/18 祝贺课题组李如雪同学的文章被Communications Chemistry 录用,论文题目为:A cascade double 1,4-addition/intramolecular annulation strategy for expeditious assembly of unsymmetrical dibenzofurans

2020/09/20 欢迎徐可可同学加入课题组。

2020/06/30 祝贺谢梦情同学通过硕士论文答辩并获得硕士学位,感谢谢梦情同学为课题组所做的贡献,祝前程似锦!

2020/06/08 祝贺课题组武玉豪同学的文章被Synthetic Communications 录用,论文题目为:“Rh-catalyzed C–N coupling of N-sulfonyl-1,2,3-trizales with secondary amines for regioselective synthesis of phenylvinyl-1,2-diamines”

2020/05/21 祝贺课题组谢梦情同学的文章被Organic Letters录用,论文题目为:Organocatalytic Approach for Assembling Flavanones via a Cascade 1,4-Conjugate Addition/oxa-Michael Addition between Propargylamines with Water

 2020/02/09 祝贺课题组唐强同学的文章被Applied Organometallic Chemistry 录用,论文题目为:“Selective synthesis of 2-(5-oxo-1-arylhex-1-yn-3-yl)phenyl benzoates via FeCl3-mediated cascade reactions of propargylamines with β-enamino ketones”

 2019/09/01 欢迎段嘉晖同学加入课题组。

 2019/08/21 祝贺课题组谢梦情同学的文章被The Journal of Organic Chemistry 录用,论文题目为:“Catalyst-Free Synthesis of 2,3-Dihydrobenzofurans via a Formal [4+1] Annulation of Propargylamines with Sulfur Ylides”。

 2019/03/08 祝贺课题组武玉豪同学的文章被Synthetic Communications 录用,论文题目为:“Transition Metal- and Oxidant-Free Sulfonylation of 1-Sulfonyl-1H-1,2,3-triazoles to Enols for the Synthesis of Sulfonate Derivatives”。

 2018/10/30 祝贺课题组武玉豪同学获得2018年研究生国家奖学金!

 研究领域

      本课题组主要从事过渡金属催化的多组分串联反应和基于邻亚甲基苯醌(o-AQMs)1,4-共轭加成/分子内环化串联反应合成杂环化合物的研究。近年来主要围绕具有多反应位点的高活性反应中间体o-AQMs的化学转化及其反应性开展相关研究,发展了其与不同亲核试剂(2-萘酚、苯甲酰硫叶立德、α-羰基活泼亚甲基化合物等)1,4-共轭加成/分子内环化串联新反应及多种结构新颖含氧杂环化合物的合成新方法,研究成果先后在Org. Lett., Chem. Commun., Adv. Synth. Catal., J. Org. Chem., Org. Biomol. Chem., TetrahedronSCI核心期刊上发表。同时在过渡金属催化的重氮化合物的C-H官能化和环加成反应等方面也开展了部分研究工作,并取得了一定研究结果。





 代表性论文

2023年

77. Yinyin Feng, Guanghao Shi, Liwei Xiang, Wangcheng Hu, Xinwei He,* and Yongjia Shang.* Access to tetrahydrophenanthridine N-oxides via Rh(III)-catalyzed cascade C-H activation/cyclization of cyclic 2-diazo-1,3-diones and aryloximes. Tetrahedron, 2023, 144, 133584.

76. Hao Wu, Shuguang Chen,* Dengmengfei Xiao, Feng Li, Kaiyuan Zhou, Xiaocui Yin, Chunni Liu, Xinwei He, Yongjia Shang.* Visible-Light-Mediated Deacylated Alkynylation of Unstrained Ketone. Org. Lett., 2023, 25, 1166-1171.

2022年

75. Taibei Fang, Shiwen Zhang, Qingqing Ye,* Shuwen Kong, Tingting Yang, Kaijie Tang, Xinwei He,* and Yongjia Shang.* Rh-catalyzed Cascade C-H Activation/Annulation of N-Hydroxybenzamides and Propargylic Acetates for Modular Access to Isoquinolones. Molecules, 2022, 27, 8553.

74. Xinwei He,* Ruxue Li, Pui Ying Choy, Jiahui Duan, Zhenzhen Yin, Keke Xu, Qiang Tang, Rong-Lin Zhong, Yongjia Shang* and Fuk Yee Kwong.* An expeditious FeCl3-catalyzed cascade 1,4-conjugate addition/annulation/1,5-H shift sequence for modular access of all-pyrano-moiety-substituted chromenes. Chem. Sci., 2022, 13, 13617-13622.

73. Xinwei He,* Keke Xu, Yanan Liu, Demao Wang, Qiang Tang, Wenjie Hui, Haoyu Chen, and Yongjia Shang. Radical-Induced Cascade Annulation/Hydrocarbonylation for Construction of 2-Aryl-4H-chromen-4-ones. Molecules, 2022, 27, 7412.

72. Qiang Tang, Keke Xu, Xinwei He,* and Yongjia Shang.* Metal-Free Cascade 1,4-Conjugate Addition/Selective Annulation Strategy for Divergent Synthesis of Polysubstituted Imidazoles and 4-Alkenylquinazolines. Adv. Synth. Catal., 2022, 364, 4103-4109.

71. Tianyi Liu, Kin Boon Gan, Rong-Lin Zhong, Xinwei He,* and Fuk Yee Kwong.* A Metal-Free and Redox-Neutral Benzylic C−O Cyclization for Succinct Access of Helical Chromenes. Org. Lett., 2022, 24, 6805-6809. (The publication is highlighted by Synfacts. Read more about Synfacts)

70. Mingzhou Shang, Lanlan Zhang, Miaomiao Chen, Wangcheng Hu, Xinwei He,* Hongjian Lu. Modular Access to Esterified/Fused Isocoumarins via Rh-catalyzed C-H Activation/Transannulative Coupling/Annulation of Phthalic Anhydrides with Cyclic 2-Diazo-1,3-diketones and Methanol. Chin. J. Org. Chem., 2022, 42, 3816-3823.

69. Wenbo Hu, Liqin Yan, Youpeng Zuo, Shuwen Kong, Yue Pu, Qiang Tang, Xinyu Wang, Xinwei He,* Yongjia Shang.* Rhodium(III)-Catalyzed Three-Component Cascade Annulation for Modular Assembly of N-Alkoxylated 3-Arylisoindolin-1-ones with Tetrasubstituted Carbon Center. Adv. Synth. Catal., 2022, 364, 2589-2595.

68. Yinsong Wu, Enshen Zhang, Jiahui Duan, Keke Xu, Xinwei He,* Yongjia Shang.* Assembly of Pyran-Fused Isoquinolines via Rhodium-Catalyzed Double Annulations of Methyl Benzimidates with Diazo Compounds. Synthesis, 2022, 54,4583-4591.

67. Chenli Fan, Ruxue Li, Jiahui Duan, Keke Xu, Yanan Liu, Demao Wang, Xinwei He.* Meldrum's acid-induced and FeCl3-catalyzed one-pot domino reactions for construction of bis(indolyl)methanes. Synth. Commun., 2022, 52, 1155-1164.

66. Lili Yuan, Lanlan Zhang, Youpeng Zuo, Guang Han, Xinwei He,* Yongjia Shang.* Rh(Iii)-Catalyzed Cascade C-H Activation/Annulation of Cyclic 2-Diazo-1,3-Diketones With Benzoylacetonitriles to Polycyclic Benzo[de]chromenes. Heterocycles, 2022, 104, 764-775.

65. Yi Ling Tsang, Pui Ying Choy, Man Pan Leung, Xinwei He, Fuk Yee Kwong.* Recent advances in rhodium-catalysed crossdehydrogenative-coupling between two C(sp2)–H bonds. Org. Chem. Front., 2022, 9, 1992–2012.

64. Qiang Tang, Meng Yuan, Jiahui Duan, Keke Xu, Ruxue Li, Mengqing Xie, Shuwen Kong, Xinwei He,*  Yongjia Shang.* Metal-free Cascade Annulation Approach for Modular Assembly of Alkynyl/Benzoyl Functionalized Quinolines. Eur. J. Org. Chem., 2022, e202101285.

2021年

63. Jiahui Duan, Xinwei He,* Pui Ying Choy, Qi Wang, Mengqing Xie, Ruxue Li, Keke Xu, Yongjia Shang,* Fuk Yee, Kwong.* Cascade Lactonization/Benzannulation of Propargylamines with Dimethyl 3-Oxoglutarate for Modular Assembly of Hydroxylated/Arene-Functionalized Benzo[c]chromen-6-ones. Org. Lett., 2021, 23, 6455-6460.

62. Yinsong Wu, Xinwei He,* Mengqing Xie, Ruxue Li, Yi Ning, Jiahui Duan, Enshen Zhang, Yongjia Shang.* Rh(III)-Catalyzed Cascade Nucleophilic Addition/Annulation of 2Diazo-1,3-diketones with 1,3-Dicarbonyl Compounds To Access 6,7-Dihydrobenzofuran-4(5H)-ones. J. Org. Chem., 2021, 86, 7370-7380.

61. Xinwei He,* Ruxue Li, Pui Ying Choy, Mengqing Xie, Jiahui Duan, Qiang Tang, Yongjia Shang,* Fuk Yee, Kwong.* A Cascade Double 1,4-Addition/Intramolecular Annulation Strategy for Expditious Assembly of Unsymmetrical Dibenzofurans. Commun. Chem., 2021, 4, 42. (DOI: 10.1038/s42004-021-00478-2)

60. Li-Qin Yan, Zhenzhen Yin, Xinwei He,* Qianqian Li, Ruxue Li, Jiahui Duan, Keke Xu, Qiang Tang, and Yongjia Shang.* Copper-Catalyzed Cascade 1,4-Addition/Annulation/Hydrolysis of Propargylamines with 2Hydroxynaphthalene-1,4-diones: Direct Formation of 12-Phenacyl-11Hbenzo[b]xanthenes. J. Org. Chem., 2021, 86, 4182-4192. (Highlighted by CBG资讯 人物与科研https://www.chembeango.com/zixun/54582)

59. Youpeng Zuo, Xinwei He,* Qiang Tang, Wangcheng Hu, Tongtong Zhou, Wenbo Hu, Yongjia Shang.* Palladium-Catalyzed 5-exo-dig Cyclization Cascade, Sequential Amination/Etherification for Stereoselective Construction of 3-Methyleneindolinones. Adv. Synth. Catal., 2021, 363, 2117-2123. 

58. Wangcheng Hu, Xinwei He,* Tongtong Zhou, Youpeng Zuo, Shiwen Zhang, Tingting Yang, Yongjia Shang.* Construction of Isoxazolone-Fused Phenanthridines via Rh-Catalyzed Cascade C-H Activation/Cyclization of 3-Arylisoxazolones with Cyclic 2-Diazo-1,3-diketones. Org. Biomol. Chem., 2021, 19, 552-556.

57. Tongtong Zhou, Xinwei He,* Youpeng Zuo, Yuhao Wu, Wangcheng Hu, Shiwen Zhang, Jiahui Duan and Yongjia Shang.* Rh-catalyzed formal [3+2] cyclization for synthesis of 5-aryl-2-(quinolin-2-yl)oxazoles and its applications in metal ions probes. Chin. J. Chem., 2021, 39, 621-626.

2020年

56. Xinwei He,* Ruxue Li, Pui Ying Choy, Tianyi Liu, Junya Wang, On Ying Yuen, Man Pan Leung, Yongjia Shang, Fuk Yee, Kwong.* DMAP-Catalyzed Annulation Approach For Modular Assembly of Furan-Fused Chromenes. Org. Lett., 2020, 22, 9444-9449. (Highlighted by CBG资讯 人物与科研https://www.chembeango.com/zixun/54002)

55. Xinwei He,* Ruxue Li, Pui Ying Choy, Tianyi Liu, On Ying Yuen, Man Pan Leung, Yongjia Shang, Fuk Yee Kwong.* Rapid Access of Alkynyl and Alkenyl Coumarins via a Dipyridinium Methylide and Propargylamine Cascade Reaction. Org. Lett., 2020, 22, 7348-7352.

54. Xinwei He,* Ruxue Li, Mengqing Xie, Jiahui Duan, Qiang Tang, Yongjia Shang.* Copper-Catalyzed Cascade Three-Component Azide–Alkyne Cycloaddition/Condensation/ Transesterification: Easy Access to 3-Triazolylcoumarins. New J. Chem., 2020, 44, 12266-12273.

53. Xinwei He,* Yuhao Wu, Tongtong Zhou, Youpeng Zuo, Mengqing Xie, Ruxue Li, Jiahui Duan, Yongjia Shang. Rh-catalyzed C–N coupling of N-sulfonyl-1,2,3-trizales with secondary amines for regioselective synthesis of phenylvinyl-1,2-diamines. Synth. Commun., 2020, 50, 2685-2697.

52. Xinwei He,* Mengqing Xie, Ruxue Li, Pui Ying Choy, Qiang Tang, Yongjia Shang, Fuk Yee Kwong.* Organocatalytic Approach for Assembling Flavanones via a Cascade 1,4-Conjugate Addition/oxa-Michael Addition between Propargylamines with Water. Org. Lett. 2020, 22, 4306-4310. (Highlighted by CBG资讯 人物与科研https://www.chembeango.com/zixun/50339).

51. Xinwei He,* Cheng Yang, Yinsong Wu, Mengqing Xie, Ruxue Li, Jiahui Duan, Yongjia Shang.* Synthesis of Unsymmetrical Urea Derivatives via One-Pot Sequential Three-Component Reactions of Cyclic 2-Diazo-1,3-diketones, Carbodiimides, and 1,2-Dihaloethanes. Org. Biomol. Chem., 2020, 18, 4178-4182.

50. Qiang Tang, Xinwei He,* Jinxue Zhang, Tongtong Zhou, Mengqing Xie, Ruxue Li, Youpeng Zuo, Yongjia Shang.* Selective Synthesis of 2-(5-Oxo-1-arylhex-1-yn-3-yl)phenyl Benzoates via FeCl3-Mediated Cascade Reactions of Propargylamines with β-Enamino Ketones. Appl. Orgnometal. Chem., 2020, 34, ASAP (DOI: 10.1002/aoc.5676).

49. Youpeng Zuo, Xinwei He,* Qiang Tang, Wangcheng Hu, Tongtong Zhou, Yongjia Shang.* Palladium-Catalyzed Cascade Decarboxylative Amination/6-endo-dig Benzannulation of o-Alkynylarylketones with N-Hydroxyamides To Access Diverse 1-Naphthylamine Derivatives. Org. Lett., 2020, 22, 3890-3894.

48. Yi Ning, Xinwei He,* Youpeng Zuo, Jian Wang, Qiang Tang, Mengqing Xie, Ruxue Li, Yongjia Shang.* Rh-Catalyzed C-H Activation/Intramolecular Condensation for Construction of Benzo[f]pyrazolo[1,5-a][1,3]diazepines. Org. Biomol. Chem., 2020, 18, 2893-2901.

47. Chen Yang, Chen Chen, Shunfan Li, Xinwei He, Youpeng Zuo, Wangcheng Hu, Tongtong Zhou, Jian Wang,* Yongjia Shang.* Rh(III)-Catalyzed Relay Double Carbenoid Insertion and Diannulation of Sulfoximine Benzamides with α-Diazo Carbonyl Compounds: Access to Furo[2,3-c]isochromenes. Org. Lett.2020, 22, 2506-2511.

2019

46. Xinwei He, Pui Ying Choy, Man Pan Leung, On Ying Yuen, Tianyi Liu, Yongjia Shang, Fuk Yee Kwong.* A ZnI2-Catalyzed Regioselective Cascade 1,4-Conjugate Addition/5-exo-dig Annulation Pathway for One-Pot Access to Heterobiaryl Frameworks. Chem. Commun., 2019, 55, 15069-15072.

45. Xinwei He,* Mengqing Xie, Qiang Tang, Youpeng Zuo, Ruxue Li, and Yongjia Shang.* Catalyst-Free Synthesis of 2,3-Dihydrobenzofurans via a Formal [4+1] Annulation of Propargylamines with Sulfur Ylides. J. Org. Chem., 2019, 84, 11623−11638.

44. Youpeng Zuo, Xinwei He,* Yi Ning, Qiang Tang, Mengqing Xie, Wangcheng Hu and Yongjia Shang.* Substituent-Oriented C–N Bond Formation via N–H Insertion or Wolff Rearrangement of 5-Aryl-1H-pyrazoles and Diazo Compounds. Org. Biomol. Chem., 2019, 17, 9766–0771.

43. Qianqian Li, Xinwei He,* Jiajia Tao, Mengqing Xie, Hui Wang, Ruxue Li, and Yongjia Shang.* Base-mediated 1,4-Conjugate Addition/Intramolecular 5-exo-dig Annulation of Propargylamines with Benzoylacetonitriles and β-Keto Esters for Polysubstituted Furans and Furo[3,4-c]coumarins Formation. Adv. Synth. Catal., 2019, 361, 1874-1886.

42. Yi Ning, Xinwei He, Youpeng Zuo, Panyuan Cai, Mengqing Xie, Jian Wang,* and Yongjia Shang.* Rhodium(II) Acetate-Catalysed Cyclization of Pyrazol-5-amine and 1,3-Diketone-2-diazo Compounds Using N,N-Dimethylformamide as a Carbon-Hydrogen Source: Access to Pyrazolo[3,4-b]pyridines. Adv. Synth. Catal., 2019, 361, 3518-3524.

41. Li-Qin Yan, Xiaoting Cai, Xinwei He,* Hui Wang, Mengqing Xie, Youpeng Zuo, Yongjia Shang.* Synthesis of 4-Styrylcoumarins via FeCl3-Promoted Cascade Reactions of Propargylamines with β-Keto Esters. Org. Biomol. Chem., 2019, 17, 4005–4013.

40. Xinwei He,* Yuhao Wu, Youpeng Zuo, Mengqing Xie, Ruxue Li and Yongjia Shang.* Transition Metal- and Oxidant-Free Sulfonylation of 1-Sulfonyl-1H-1,2,3-triazoles to Enols for the Synthesis of Sulfonate Derivatives. Synth. Commun., 2019, 49, 959-972.

2018

39. Xinwei He,* Guang Han, Youpeng Zuo, Yongjia Shang.* Rh(III)-catalyzed C-H Activation of Primary Benzamides and Tandem Cyclization with Cyclic 2-Diazo-1,3-diketones for the Synthesis of Isocoumarins. Tetrahedron, 2018, 74, 7082-7088.

38. Youpeng Zuo, Xinwei He, Yi Ning, Yuhao Wu, Yongjia Shang.* Selective Synthesis of Aminoisoquinolines via Rh(III)-catalyzed C-H/N-H Bond Functionalization of N-Aryl Amidines with Cyclic 2-Diazo-1,3-diketones. J. Org. Chem.201883, 13463-13472.

37. Xinwei He,* Hui Wang, Xiaoting Cai, Qianqian Li, Jiajia Tao, Yongjia Shang.* FeCl3-promoted Tandem 1,4-Conjugate Addition/6-endo-dig Cyclyzation/Oxidation of Propargylamines and Benzoylacetonitriles/Malononitrile: Direct Access to Functionalized 2-Aryl-4H-chromenes. Org. Biomol. Chem., 2018, 16, 7191-7202.

36. Chenli Fan, Xinwei He,* Yin Zuo, Yongjia Shang.* Synthesis of Oxazole and Furan Derivatives via Rh2(OAc)4-catalyzed C≡X Bond Insertion of Cyclic 2-Diazo-1,3-diketones with Nitriles and Arylacetylenes. Synth. Commun., 2018, 48, 2782-2792.

35. Xinwei He,* Yuhao Wu, Wenjing Jin, Xiaoshun Wang, Cong Wu, Yongjia Shang.* Highly Efficient AgNO3-catalyzed Approach to 2-(Benzo[d]azol-2-yl)phenols from Salicylaldehydes with 2-Aminothiophenol, 2-Aminophenol and Benzene-1,2-diamine. Appl. Orgnometal. Chem.201832, e4284.

34. Xinwei He,* Yuhao Wu, Chenli Fan, Peng Lu, Youpeng Zuo, Yongjia Shang.* Oleylamine-catalyzed Tandem Knoevenagel/Michael Addition of 1,3-Cyclohexanediones with Aromatic Aldehydes. Chem. Res. Chin. Univ., 201834, 186-190.

33. Youpeng Zuo, Xinwei He, Yi Ning, Lanlan Zhang, Yuhao Wu, Yongjia Shang.* Divergent Synthesis of 3,4-Dihydrodibenzo[b,d]furan-1(2H)-ones and Isocoumarins via Additive-controlled Chemoselective C-C or C-N Bond Cleavage. New J. Chem., 201842, 1673-1681.

32. Shuyan Yu,* Jingxin Wu, Xinwei He, Yongjia Shang.* Ferrocenyl Bisoxazoline as an Efficient Non-phosphorus Ligand for Palladium-catalyzed Copper-free Sonogashira Reaction in Aqueous Solution. Appl. Orgnometal. Chem.201832, e4156.

31. Cuie Wang,* Ning Wang, Xinhua Liu, Peng Wan, Xinwei He, Yongjia Shang.* Expanding Application of Immobilized Candida Antarctica Lipase B: A Green Enzyme Catalyst for Knoevenagel Condensation Reaction. Fibers and Polymers, 2018, 19, 1611-1617.

2017

30. Youpeng Zuo, Xinwei He, Yi Ning, Yuhao Wu, Yongjia Shang.* Rh(III)-Catalyzed C-H Activation/Intramolecular Cyclization: Access to N-Acyl-2,3-dihydro-1H-carbazol-4(9H)-ones from Cyclic 2-Diazo-1,3-diketones and N-Arylamides. ACS Omega, 2017, 2, 8507-8516.

29. Xinwei He,* Jiajia Tao, Hui Wang, Xiaoting Cai, Qianqian Li, Yongjia Shang.* Synthesis of polysubstituted phenyl acetates via FeCl3-mediated domino reaction of 2-(aryl(piperidin-1-yl)methyl)phenols and 1,3-diketones. Tetrahedron, 2017, 73, 7017-7023.

28. Xinwei He,* Zhiyu Yu, Youpeng Zuo, Cheng Yang, Yongjia Shang.* Direct Carboxamidation of Cyclic 2-Diazo-1,3-diketones by Rh2(OAc)4-catalyzed Isocyanide Insertion-Hydrolysis. Org. & Biomol. Chem.201715, 7127-7130.

27. Cheng Yang§, Xinwei He§ (co-first author), Lanlan Zhang, Guang Han, Youpeng Zuo, Yongjia Shang.* Synthesis of Isocoumarins from Cyclic 2-Diazo-1,3-diketones and Benzoic Acids via Rh(III)-catalyzed C-H Activation and Esterification. J. Org. Chem., 2017, 82, 2081-2088.

26. Guanghao Shi, Xinwei He, Yongjia Shang,* Cheng Yang, Liwei Xiang. Oxidative Rearrangement of Isatins with Arylamines Using H2O2 as Oxidant: A Facile Synthesis of Quinazoline-2,4-diones and Evaluation of Their Antibacterial Activity. Chin. J. Chem., 2017, 35, 1835-1843. 

25. Cuie Wang, Xinwei He, Xinhua Liu, Yongjia Shang.* DMAP-catalyzed cyclization of Schiff bases with alpha-halo ketones: Synthesis of 1,4-benzoxazines. Synth. Commun., 2017, 47, 878-885.

24. Zhiqin Zhang, Xinwei He, Yongjia Shang,* Zhiyu Yu, Sufan Wang, Fuli Wu. Ferrocenyl-isoxazole Derivative: A Novel Electrochemical, Colorimetric, and Fluorescent Multiple Signal Probe for Highly Selective Recognition of Cu2+ Ions. Chem. Res. Chin. Univ., 201733, 31-35.

2016

23. Xinwei He, Yao Zhou, Yongjia Shang,* Cheng Yang, Youpeng Zuo. Synthesis of 2-Arylimino-6,7-dihydrobenzo[d][1,3]oxathiol-4(5H)-ones via Rh2(OAc)4-catalyzed Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates. ACS Omega, 2016, 1, 1277-1283.

22. Xinwei He§, Jiajia Tao§ (co-first author), Xiaoqian Hu, Hui Wang, Yongjia Shang.* FeCl3-mediated One-pot Domino Reactions for the Synthesis of 9-Aryl/9-Arylethynyl-2,3,4,9-tetrahydro-1H-xanthen-1-ones from Propargylic amines/Diaryl Amines and 1,3-Cyclohexanediones. J. Org. Chem., 201681, 2062-2069.

21. 何心伟,* 胡小倩陶佳佳韩光商永嘉.* 铁配合物催化的有机反应研究进展有机化学, 201636, 1465-1483.

20. Guanghao Shi, Xinwei He, Yongjia Shang,* Meihua Xie.* Combinatorial Synthesis of Spiro[indoline-3,2'-pyrrole] Derivatives via a Three-component Reaction under Catalyst-free Conditions. RSC Adv., 20166, 10412-10418.

19. Guanghao Shi, Xinwei He, Yongjia Shang,* Liwei Xiang, Cheng Yang, Guang Han, Bing Du.* Synthesisof 3',4'-Diaryl-4'H-spiro[indoline-3,5'-[1',2',4']oxadiazol]-2-ones via DMAP-catalyzed Domino Reactions and Their Antibacterial Activity. Chin. J. Chem., 2016, 34, 901-909.

18. Chenli Fan, Xinwei He, Kaisheng Liao, Cuie Wang, Yongjia Shang.* DMAP-catalyzed Cascade Reaction for Efficient Synthesis of Naphthofurans. Chem. Res. Chin. Univ., 2016, 32, 62-67.

17. 何心伟,* 陆鹏谢慧敏查陶春商永嘉无催化剂下2-氨基-3-氰基-5-氧代-5,6,7,8-四氢色烯衍生物的三组分合成信阳师范学院学报 (自然科学版)201629, 233-236.

2015

16. Xinwei He, Yongjia Shang,* Yao Zhou, Zhiyu Yu, Guang Han, Wenjing Jin, Jiaojiao Chen. Synthesis of Coumarin-3-carboxylic Esters via FeCl3-Catalyzed Multicomponent Reaction of Salicylaldehydes, Meldrum’s Acid and Alcohols. Tetrahedron, 2015, 71, 863-868.

15. Yongjia Shang,* Xiaoqian Hu, Xinwei He, Jiajia Tao, Guang Han, Fuli Wu, Jie Wang. FeCl3-Mediated Synthesis of  β-Alkynyl Ketones via Domino Nucleophilic-Substitution/Intramolecular-Cyclization/Reverse Claisen Condensation of  N-Cyclohexyl Propargylamines and 1,3-Diketones. J. Org. Chem., 2015, 80, 4760-4765.

2014

14. Xinwei He, Yongjia Shang,* Zhiyu Yu, Mei Fang, Yao Zhou, Guang Han, Fuli Wu. FeCl3-Catalyzed Four-component Nucleophilic Addition/Intermolecular Cyclization Yielding Polysubstituted Pyridine Derivatives. J. Org. Chem., 2014, 79, 8882-8888.

13. Xinwei He, Zhenglei Yan, Xiaoqian Hu, Yin Zuo, Chang Jiang, Lei Jin, Yongjia Shang.* FeCl3-Catalyzed Cascade Reaction: An Efficient Approach to Functionalized Coumarin Derivatives. Synth. Commun., 201444,1507-1514.

12. Manman Hu, Xinwei He, Zhiqiang Niu, Zhenglei Yan, Fuyin Zhou, Yongjia Shang.* Synthesis of 3,4,5-Trisubstituted Isoxazoles by 1,3-Dipolar Cycloaddition Reaction from α-Azidoacrylates and Aromatic Oxime. Synthesis, 201446, 510-514.

11. Zhiqiang Niu, Xinwei He, Yongjia Shang.* Efficient Enantioselective Synthesis of Dihydropyrans via Organocatalytic Michael Addition Reaction. Tetrahedron: Asymmetry, 2014, 25, 796-801.

10. 何心伟周尧于智宇方梅商永嘉. 2,5-二吡啶基-1,3,4-噁二唑的合成. 阜阳师范学院学报(自然科学版), 201431,26-28.

9. 靳文静韩光何心伟,* 胡凯商永嘉异腈参与的多组分反应新进展合成化学研究, 20142,11-22.

2013

8. Yongjia Shang,* Kaisheng Liao, Xinwei He, Jinsong Hu. One-Pot Synthesis of Disulfide-linked N-Sulfonylazetidin-2-imines via a Copper-catalyzed Multicomponent Cascade Reaction. Tetrahedron, 2013, 69, 10134-10138.

7. Jiaping Wu, Yongjia Shang,* Cuie Wang, Xinwei He, Zhenglei Yan, Manman Hu, Fuyin Zhou. Synthesis of 3,4-Dihydro-2H-1,4-Benzo[b]thiazine Derivatives via DABCO-Catalyzed One-Pot Three-Component Condensation Reactions. RSC Adv., 2013, 3, 4643-4651.

6. 何心伟朱东盛蒋畅商永嘉.* 室温无溶剂无催化剂下的Knoevenagel缩合反应研究有机化学研究, 20131, 9-12.

2012

5. Xinwei He, Yongjia Shang,* Jinsong Hu, Kai Ju, Wei Jiang, Sufang Wang. Syntheses of N-sulfonyl-N,N-disubstitutedAmidines via a Three-component Free-radical Coupling Reaction of Tertiary Amines and Arenesulfonyl Azides with Terminal Alkynes, Sci. China Chem., 2012, 55, 214-222.

4. Yongjia Shang,* Lifen Wang, Xinwei He, Min Zhang. Novel Syntheses of Pyrrolo[2,1-a]isoquinolines via 1,3-Dipolar Cycloaddition between N-Ylides and Alkynes. RSC Adv., 2012, 2, 7681-76881.

2010

3. Yongjia Shang,* Kai Ju, Xinwei He, Jinsong Hu, ShuyanYu, Min Zhang, Kaisheng Liao, Lifen Wang, Ping Zhang. Copper-Catalyzed Multicomponent Reaction: Synthesis of 4-Arylsulfonylimino-4,5-dihydrofuran Derivatives. J. Org. Chem., 2010, 75, 5743-5745.

2009

2. 何心伟 王翠娥商永嘉.* 聚乙二醇支持的2,5-二取代异噁唑啉衍生物的液相合成有机化学200929, 55-60.

1. Yongjia Shang,* Xinwei He, Jinsong Hu, Jianwei Wu, Min Zhang, Shuyan Yu, Qianqian Zhang. Copper-Catalyzed Efficient Multicomponent Reaction: Synthesis of Benzoxazoline-Amidine Derivatives. Adv. Synth. Catal., 2009351, 2709-2713.

 会议论文

10. 何心伟. 基于丙炔胺的1,4-共轭加成/环化串联反应构建含氧杂环化合物的研究第十七届江淮有机化学论坛, 中国, 台州, 2019112-4. (口头报告)

9. Mengqing Xie, Ruxue Li, Qiang Tang, Xinwei He.* Catalyst-Free Synthesis of 2,3-Dihydrobenzofurans via a Formal [4+1] Annulation of Propargylamines with Sulfur Ylides. 第十一届全国有机化学学术会议, 中国, 上海, 2019831-93.

8. Xinwei He,* Jiajia Tao, Hui Wang, Yongjia Shang.* Synthesis of Polysubstituted Phenyl Acetates via FeCl3-mediated Domino Reaction of 2-(Aryl(piperidin-1-yl)methyl)phenols and 1,3-Diketones. 第十届全国有机化学学术会议, 中国, 深圳, 20171219-21.

7. Youpeng Zuo, Xinwei He, Yongjia Shang.* Divergent Synthesis of 3,4-Dihydrodibenzo[b,d]furan-1(2H)-ones and Isocoumarins via Additive-controlled Chemoselective C-C or C-N Bond Cleavage. 第十届全国有机化学学术会议, 中国, 深圳, 20171219-21.

6. Xinwei He, Yao Zhou, Yongjia Shang.* Synthesis of 2-Iimino-[1,3]oxathioles via Rh2(OAc)4-catalyzed [3+2] Cycloaddition Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates. 第十九届全国金属有机化学学术讨论会中国杭州, 20161028-31.

5. Xinwei He, Xiaoqian Hu, Jiajia Tao, Hui Wang, Xiaoting Cai, Yongjia Shang.* FeCl3-catalyzed Domino Reactions of Propargylic Amines and Activated Methylene Compounds. 第十三届全国有机合成化学学术研讨会, P29, 中国扬州, 20161013-16. (口头报告).

4. Xiaoqian Hu, Xinwei He, Jiajia Tao, Yongjia Shang.* FeCl3-catalyzed One-pot Tandem Reactions of N-cyclohexyl Propargylamines and 1,3-Diketones. 第九届全国有机化学学术会议, P360, 中国长春, 2015728-31.

3. 何心伟商永嘉.* FeCl3催化的基于芳醛、活泼亚甲基化合物的一锅串联反应/多组分反应合成香豆素/吡啶衍生物的研究第十二届江淮有机化学论坛中国芜湖, 20141031-112.

2. 何心伟, 朱东盛, 蒋畅, 商永嘉.* 室温无溶剂无催化剂下的Knoevenagel缩合反应研究. 第八届有机化学学术会议暨首届重庆有机化学国际研讨会, P794, 中国, 重庆, 20131017-20.

1. Xinwei He, Kaisheng Liao, Zhenglei Yan, Fuyin Zhou, Manman Hu, Yongjia Shang.* One-step Synthesis of Polysubstituted N-Sulfonylazetidin-2-imines via Copper-catalyzed Sequential Multicomponent/S-S Coupling Reaction. 第十七届全国金属有机化学学术讨论会, P209, 中国, 北京, 20121019-22.

 

7. 叶青青, 左有鹏, 何心伟, 商永嘉. 1,2,3-三取代中氮茚衍生物及其制备方法. 中国发明专利, 专利号: 201810293794.3, 公开日: 2018.09.14.

6. 李欠欠, 何心伟, 陶佳佳, 商永嘉. 多取代呋喃衍生物及其制备方法. 中国发明专利, 专利号: 201810227907.X, 公开日: 2018.08.24.

5. 武玉豪, 何心伟, 左有鹏, 商永嘉. 香豆素-4-磺酸酯衍生物及其制备方法. 中国发明专利, 专利号: 201810034868.1, 公开日: 2018.07.20.

4. 左有鹏, 何心伟, 商永嘉. 异香豆素衍生物的制备方法. 中国发明专利, 专利号: 201710416486.0, 公开日: 2017.09.01.

3. 何心伟, 靳文静, 陈娇娇, 商永嘉. 一种香豆素-3-羧酸酯衍生物的制备方法. 中国发明专利, 专利号: 201310642930.2, 公开日: 2014.03.12.

2. 何心伟, 商永嘉, 琚凯. 3,4,5-三取代噁唑烷酮类化合物及其制备方法. 中国发明专利, 专利号: 201410557565.X, 公开日: 2015.02.04.

1. 赵敏, 商永嘉, 何心伟, 孙宇. 絮凝剂组合物, 中国发明专利, 专利号: 201110222749.7, 公开日: 2011. 12. 28.

 专 著

1. Pui Ying Choy, Xinwei He, Fuk Yee Kwong.* Chapter 2: Palladacycles as Precatalysts for Heck and Sonogashira Cross-Coupling Reactions. Palladacycles: Catalysis and Beyond, Burlington: Elsevier, 2019. pp. 21-173.


 

 


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